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高分子材料系

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杨贯文

作者:时间:2025-02-27浏览次数:

杨贯文,理学博士,研究员/正高,博士生导师。主要从事仿酶催化可降解高分子创制、碳一气体的催化转化等研究。以第一作者或通讯作者在Chem. Rev.、Acc. Chem. Res.、Nat. Synth.、J. Am. Chem. Soc. (3)、Angew. Chem. Int. Ed. (4)、Macromolecules (4)等期刊发表研究和综述论文25篇,近五年论文被引用1100余次,H-index为24。授权国家发明专利9项、美国发明专利1项。主持国家自然科学基金、中国博士后基金等项目。

 

教育经历:

2017.09-2020.09 浙江大学高分子化学与物理博士

2010.09-2013.06 大连理工大学有机化学硕士

2006.09-2010.06 济南大学化学工程与工艺学士

 

工作经历:

2023.03-2025.01 浙江大学高分子科学与工程学系副研究员

2020.10-2023.02 浙江大学高分子科学与工程学系博士后

2016.04-2017.08 浙江大学高分子科学与工程学系研究助理

2013.10-2016.01 山东威智医药工业有限公司,生产部,中试组长

 

 

研究方向:

1. 新型仿酶催化剂的设计与合成

2. 二氧化碳/一氧化碳的催化转化

3. 可循环/可降解高分子的创制

4. 增材制造与新材料加工成型

 

 

招生/招聘情况:

每年可招1名博士研究生,≥3名硕士研究生

面向海内外招聘博士后、讲师、特聘副研究员/研究员

 

 

联系方式:

地址:浙江省杭州市下沙高教园区浙江理工大学18号楼613室

电话:13067883159

邮箱:yangguanwen@topbc.net

 

 

代表性论文:

 

  1. Xie, D.; Jia, Z.-H.; Zhang, Y.-L.; Cai, X.-L.; Liu, L.-N.; Yang, G.-W.*; Kang, X.*; Zhang, X.; Zhang, Y.-Y.*, Switchable Polymerization from Monomer Mixtures to Synthesize Oxygen-Rich Block Copolymers with Dual Recyclability and Degradability. Angew. Chem. Int. Ed. 2025, e202424856.

  2. Chen, Z.; Yang, G.-W.*; Wu, T.; Qian, Z.; Wu, G.-P.*, Dual Kinetic Control of Polycarbonate Sequences via Breaking Catalysis Symmetry Using Dual Biomimetic Organoboron Catalysts. Macromolecules 2025, 58, 1349–1356.

  3. Yang, G.-W.; Xie, R.; Zhang, Y.-Y.; Xu, C-K.; Wu, G.-P.*, Evolution of Copolymers of Epoxides and CO2: Catalysts, Monomers, Architectures, and Applications. Chem. Rev. 2024, 124, 12305–12380.

  4. Xu, C-K.; Lu, C.; Zhao, S.; Yang, G.-W.*; Li, W.; Wang, J.; Wu, G.-P.*, Rational Optimization of Ammonium and Phosphonium Cations of Bifunctional Organoborane Catalysts for Copolymerization of Propylene Oxide with CO2 to Afford Poly(propylene carbonate). Macromolecules 2024, 57, 9076–9087.

  5. Xie, R.; Wang, Y.; Li, S.; Li, B.; Xu, J.; Liu, J.; He, Y.; Yang, G.-W.*; Wu, G.-P.*, Insights into the Distinct Behaviors between Bifunctional and Binary Organoborane Catalysts through Terpolymerization of Epoxide, CO2, and Anhydride. Angew. Chem. Int. Ed. 2024, 63, e202404207.

  6. Yang, G.-W.; Xu, C-K.; Xie, R.; Zhang, Y.-Y.; Lu, C.; Qi, H.; Yang, L.; Wang, Y.; Wu, G.-P.*, Precision Copolymerization of CO2 and Epoxides Enabled by Organoboron Catalysts. Nat. Synth. 2022, 1, 892−901.

  7. Zhang, Y.-Y.; Yang, G.-W.*; Xie, R.; Zhu. X-F.; Wu, G.-P.*, Sequence-Reversible Construction of Oxygen-Rich Block Copolymers from Epoxide Mixtures by Organoboron Catalyst, J. Am. Chem. Soc. 2022, 144, 19896–19909.

  8. Yang, G.-W.#; Wang, Y.#; Qi, H.; Zhang, Y.-Y.; Zhu, X-F.; Lu, C.; Yang, L.; Wu, G.-P.*, Exclusive Preparation and Depolymerization of Chemically Recyclable CO2 Plastics Enabled by Dinuclear Organoboron Catalysts. Angew. Chem. Int. Ed. 2022, 61, e202210243.

  9. Qi, H.; Xie, R.; Yang, G.-W.*; Zhang, Y.-Y.; Xu, C.-K.; Wang, Y.; Wu, G.-P.*, Rational Optimization of Bifunctional Organoboron Catalysts for Efficient Ring-Opening Polymerization of Epoxides, Macromolecules 2022, 55, 9081–9090.

  10. Yang, G.-W.; Zhang, Y.-Y.; Wu, G.-P.*, Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity. Acc. Chem. Res. 2021, 54, 4434−4448.

  11. Yang, G.-W.; Xu, C.-K.; Xie, R.; Zhang, Y.-Y.; Zhu, X.-F., Wu, G.-P.*, Pinwheel-Shaped Tetranuclear Organoboron Catalysts for Perfectly Alternating Copolymerization of CO2 and Epichlorohydrin. J. Am. Chem. Soc. 2021, 143, 3455–3465.

  12. Yang, G.-W.; Zhang, Y.-Y.; Xie, R.; Wu, G.-P.*, Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO2 and Epoxides with Unprecedented Efficiency. J. Am. Chem. Soc. 2020, 142, 12245–12255.

  13. Yang, G.-W.#; Zhang, Y.-Y.#; Xie, R.; Wu, G.-P.*, High‐Activity Organocatalysts for Polyether Synthesis via Intramolecular Ammonium Cation Assisted SN2 Ring‐Opening Polymerization. Angew. Chem. Int. Ed. 2020, 59, 16910–16917.

  14. Yang, G.-W.; Zhang, Y.-Y.; Wang, Y.-Y.; Wu, G.-P.*; Xu, Z.-K.; Darensbourg, D. J.*, Construction of Autonomic Self-Healing CO2-Based Polycarbonates via One-Pot Tandem Synthetic Strategy. Macromolecules 2018, 51, 1308–1313.